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Desulphurisation equipment

In the extraction and processing of natural gas and unconventional natural gas such as shale gas and coal bed methane, the presence of hydrogen sulphide (H₂S) not only corrodes the equipment and pollutes the environment, but also poses a serious threat to the safety of production and the quality of the end-use gas. In order to ensure the efficient use of natural gas, desulphurisation technology has become a key link. At present, the mainstream desulphurisation methods in the industry are mainly divided into two categories: dry desulphurisation and wet desulphurisation, which meet diversified industrial needs with different technical advantages.

    Dry desulfurization

    Efficient and stable ‘solid state purification’ programme
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    Dry desulphurisation takes fixed-bed desulphurisation tower as the core device, which is filled with oxidising desulphurising agents such as iron oxide and activated carbon. When the sulphur-containing raw gas passes through the desulphurisation tower, H₂S undergoes redox reaction with the desulphurising agent, and is adsorbed and converted into sulphide and fixed in the bed, thus realising deep desulphurisation. This process has the characteristics of simple process, convenient operation, no need for complex liquid circulation system, etc. It is especially suitable for processing gas with small volume and low sulphur content, and is widely used in remote gas wells and small gas stations. In addition, dry desulphurisation has high operational stability and strong adaptability to fluctuations in working conditions, which can continuously guarantee the purification effect.

    Wet desulfurization

    Wet desulphurisation: recycling ‘liquid purification’ system
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    Wet FGD adopts the principle of gas-liquid absorption, after the sulphur-containing raw gas enters the absorption tower, H₂S and the desulphurisation liquid (such as alcohol-amine solution and quebracho solution) sprayed in the tower will fully contact with each other and undergo a chemical reaction, which will be rapidly absorbed and removed, and the purified gas will be fed into the downstream process. After absorbing H₂S, the desulphurisation rich liquid enters the regeneration tank under reduced pressure, and under the action of air oxidation, H₂S is converted into sulphur monomers to form a foamy suspension. The sulphur foam is extracted through the separation equipment, and finally formed into solid sulphur for export after settling, heating and melting processes. At the same time, the desulphurisation liquid restores its activity and becomes poor liquid, which is pressurised by the poor liquid pump and returned to the absorption tower for recycling. Although the process is complex, it has a large treatment capacity and high desulphurisation efficiency, and can be adapted to high sulphur content working conditions.

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